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研究了在 GaAs (111)衬底上生长的六角相 GaN的极性的相关关系。在高 Ⅴ /Ⅲ比的条件下用MOVPE和MOMBE方法生长的GaN的极性和GaAs衬底的极性一致;在(111)A-Ga表面上的生长层呈现Ga的极性,而在(111)B-As表面上的生长层呈现N的极性。然而,在低的Ⅴ /Ⅲ比,或采用一个AIN中间层的条件下,用HVPE和MOMBE方法在GaAs(111)B表面上生长的GaN呈现出Ga的极性。目前,其原因尚不清楚,但是这些结果表明采用HVPE生长方法或用一高温AlN阻挡层可以得到高质量的GaN。
The relationship between the polarities of hexagonal GaN grown on GaAs (111) substrates was investigated. The polarity of GaN grown by the MOVPE and MOMBE methods at high V / III ratio is consistent with the polarity of the GaAs substrate; the growth layer on the (111) A-Ga surface exhibits the polarity of Ga, 111) The growth layer on the B-As surface exhibits N polarity. However, GaN grown on the surface of GaAs (111) B by the HVPE and MOMBE methods exhibits a Ga polarity at a low V / III ratio or using an AIN interlayer. At present, the reason for this is not clear, but these results indicate that high-quality GaN can be obtained by HVPE growth method or by using a high-temperature AlN barrier layer.