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据《机械科学与技术》1996年第3期叶林报道:研制了一种聚合物——聚芳胺吠喃(PAF)。在这种聚合物的分子中含有大量的(C_6H_6N)、(-C_4H_2O-)等含氮的并富含双键的基团。用烷基化试剂将其离子化,在分子链中引入离子基团,可使其导电率提高10个数量级;若再进一步用碘掺杂,其导电率可达10_-2s.cm_-1。掺杂后的聚合物呈绿色,并带有金属光泽。实验过程:将合成聚合物PAF提纯后,用溶剂溶解,加入(CH_3)_2SO_4搅拌均匀,待反应完成后,将其在玻璃片上成膜(膜厚不大于
According to “Mechanical Science and Technology” 1996 the third period Ye Lin reported: developed a polymer - polyaryl amine furan (PAF). This polymer contains a large number of (C_6H_6N), (-C_4H_2O-) and other nitrogen-containing and double-rich groups. Ionization with alkylating agents, the introduction of ionic groups in the molecular chain, the conductivity can be increased by 10 orders of magnitude; if further doping with iodine, the conductivity up to 10_-2s.cm_-1. The doped polymer is green and has a metallic luster. Experimental process: The synthesized polymer PAF purified, dissolved in a solvent, add (CH_3) _2SO_4 Stir until the reaction is completed, the film was formed on the glass (film thickness not greater than