The effects of mercury ions on gold cyanidation were studied. The results show that under low cyanide concentration, gold cyanide process is controlled by CN- transfer, while at higher cyanide concentration, there forms passivation on gold surface. Therefore, chemical oxidation of gold in cyanide solution of higher concentration is controlled by surface reaction. Small quantity of additions of mercury ions bring about great increases in anodic gold dissolution rate, decreases the passivation and reduces the equilibrium activated energy. In addition, they also markedly change the effect pattern of cyanide concentration. Mercury ions show positive effects on cathodic reduction of oxygen and raise the rate of electrochemical step of the cathodic reduction of oxygen. Addition of a certain amount of hydrogen peroxide is confirmed to be an effective way for intensification of cathodic process on gold electrode. Active potential range and current peak on anodic dissolution are enlarged when being co-intensified with Hg2+ and hydrogen peroxide. Co-intensifying effect may be obtained and gold leaching rate is considerably increased on cyanide leaching of gold from gold concentrates.