在过去的几十年里,以Mo(W)/Cu/S簇合物为前驱物进行含簇配位聚合物的自组装一直让化学工作者对此怀有浓厚的研究兴趣[1~6]。这主要是因为此类化合物不仅具有丰富的化学结构,而且在光学材料、吸附材料、生物化学等方面都具有重要的用途[7~12]。例如,含簇三维聚合物{[WSCu4(4,4′-bipy)4][WS4Cu4I4(4,4′-bipy)2]}∞不仅具有漂亮的孔洞结构, Chemists have long been interested in the self-assembly of cluster-containing polymers using Mo (W) / Cu / S clusters as precursors in the past few decades [1-6 ]. This is mainly because these compounds not only have a rich chemical structure, but also have important applications in optical materials, adsorbent materials, biochemistry, etc. [7-12]. For example, the cluster-containing three-dimensional polymer {[WSCu4 (4,4’-bipy) 4] [WS4Cu4I4 (4,4’-bipy) 2]} ∞ not only has a beautiful pore structure,