论文部分内容阅读
应用CS_2在Ag—S键中的单核插入产物(Ph_3P)_2Ag(S_2CSR)(R=C_6H_5或C_6H_2Pr_3-2,4,6)与1,2-二溴乙烷—异丙醇混合溶剂反应,生成一个中性四核银簇合物(Ph_3P)_4Ag_4Br_4,并利用X射线单晶衍射法测定其晶体结构。
The reaction of single insertion (Ph_3P) _2Ag (S_2CSR) (R = C_6H_5 or C_6H_2Pr_3-2,4,6) with 1, 2-dibromoethane and isopropanol in CS- A neutral tetranuclear silver cluster (Ph_3P) _4Ag_4Br_4 was synthesized and its crystal structure was determined by X-ray single crystal diffraction.