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在Langmuir等温吸附式的基础上,利用“有效浓度”的概念,推导出了乳化液膜体系的界面状态方程。进一步探讨了乳化液膜体系乳化溶胀与表面活性剂本身的及界面吸附状态的关系。所提出的界面状态方程预测值与实验值吻合较好。
Based on the Langmuir isothermal adsorption method, the interface state equation of emulsion liquid membrane system was deduced by the concept of “effective concentration”. The relationship between emulsion swelling and surfactant adsorption and interface adsorption state of emulsified liquid membrane system was further discussed. The predicted value of interface state equation is in good agreement with the experimental data.