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真空升华获得了两种晶态结构的酞菁锡（ＳｎＰｃ）多品薄膜．用常规吸收光谱和Ｘ射线衍射谱进行了表征和分析．观察到激子谱带的Ｂｅｔｈｅ分裂和Ｄａｖｙｄｏｖ分裂对异向性衬底上生长的ａ－ＳｎＰｃ和β－ＳｎＰｃ薄膜分别测量了偏振吸收光谱．发现其中β－ＳｎＰｃ异向膜具有明显的光学二向色性，并且当测试波长从Ｑ激子谱带的蓝侧向红侧变化时，二向色吸收轴发生９０°旋转．在５３０ｎｍ附近观察到一个新的吸收带，认为属于ＳｎＰｃ分子间电荷转移激子谱带。
Vacuum sublimation obtained two crystal structure of tin phthalocyanine (SnPc) multi-product film. Characterization and analysis were performed by conventional absorption and X-ray diffraction patterns. Polarized absorption spectra of the a-SnPc and β-SnPc films grown on an isotropic substrate were observed for Bethe splitting and Davydov splitting of excitonic bands, respectively. Among them, β-SnPc anisotropic films were found to have significant optical dichroism, and a 90 ° rotation of the dichroic absorption axis occurred when the test wavelength was changed from the blue side to the red side of the Q exciton band. A new absorption band near 530 nm was observed, which belongs to the SnPc intermolecular charge-transfer exciton band.