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本文以对-三氰基乙烯基-N,N-二烷基苯胺为模型化合物,开展共轭π电子体系分子内光致电子转移及电荷分离的研究。通过吸收光谱和荧光光谱探讨了这类分子的电荷分离作用以及在DMSO-H_2O中的簇集作用。
In this paper, p-tricyanoethenyl-N, N-dialkylaniline was used as a model compound to study the intramolecular photo-induced electron transfer and charge separation in the conjugated π-electron system. The charge separation of these molecules and the clustering effect in DMSO-H_2O were investigated by absorption and fluorescence spectra.