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A new dynamic ebulliometer is used to determine vapor-liquid equilibrium(VLE) data experimentally. In the equipment,both phases are recirculated. Its operation is a consequence of the Cotrell pump effect produced when the mixture is heated in a double-walled inverted vessel. The reliability of the apparatus is tested with the mixtures studied previously by various authors. VLE data for the binary systems of methyl acetate + methanol and the methyl acetate + ethanol at 0.5 MPa are determined. The experimental data are confirmed with the point-to-point test of van Ness,applying the Fortran program of Frendslund et al. In addition,the experimental results are com-pared with the UNIFAC(including different versions) and ASOG prediction models.
A new dynamic ebulliometer is used to determine vapor-liquid equilibrium (VLE) data experimentally. In the equipment, both phases are recirculated. Its operation is a consequence of the Cotrell pump effect produced when the mixture is heated in a double-walled pill. . The reliability of the apparatus is tested with the mixtures previously previously by various authors. VLE data for the binary systems of methyl acetate + methanol and the methyl acetate + ethanol at 0.5 MPa are determined. The experimental data are confirmed with the point-to -point test of van Ness, applying the Fortran program of Frendslund et al. In addition, the experimental results are com-pared with the UNIFAC (including different versions) and ASOG prediction models.