【摘 要】
：
In recent years,transition-metal-catalyzed inert C–H bond activation has developed rapidly and is a powerful protocol for the construction of new C–C or C–X
【机 构】
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State Key Laboratory of Applied Organic Chemistry, Lanzhou University,
【出 处】
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Science China(Chemistry)
论文部分内容阅读
In recent years,transition-metal-catalyzed inert C–H bond activation has developed rapidly and is a powerful protocol for the construction of new C–C or C–X bonds and the introduction of new functional groups.Our group has also developed a series of R2(O)P-directed Pd-catalyzed C–H functionalizations involving olefination,hydroxylation,acetoxylation,arylation,and acylation through an uncommon seven-membered cyclo-palladium pretransition state.Unlike previously used directing groups,the R2(O)P group acts as a directing group and is also involved in the construction of P,-hetero-ligands.
In recent years, transition-metal-catalyzed inert C-H bond activation has developed rapidly and is a powerful protocol for the construction of new C-C or C-X bonds and the introduction of new functional groups. Our group has also developed a series of R 2 (O) P-directed Pd-catalyzed C-H functionalizations involving olefination, hydroxylation, acetoxylation, arylation, and acylation through an uncommon seven-membered cyclo-palladium pretransition state. P group acts as a directing group and is also also involved in the construction of P, -hetero-ligands.
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