1IntroductionWe reported that layered polymer crystals are obtained by the topochemical polymerization of 1,3-diene monomers and provided as host material for organic intercalation[1]. For intercalation using various long-alkyl amines as the guest species, its reaction behavior, mechanism, characteristics, and potential to application have been clarified[2]. We also succeeded in the synthesis of several host layered polymer crystals with different tacticities and layer structures[3]. We describe here intercalation using various stereoregular poly(muconic acid)s (PMA) and n-alkylamines as the host and guest compounds, respectively. The reaction behavior and the layered structure of the obtained ammonium polymers are discussed from the viewpoint of stereochemical structure of the host polymers.