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ion reaction of H atom with (CH3)3GeH has been studied using ab initio molecular orbital theory. The kinetics calculation has been deduced using the canonical variational transition state theory (CVT) with the small-curvature tunneling correction method (SCT) over the temperature range of 200-3000 K. The CVT/SCT rate constants exhibit typical non-Arrhenius behavior, and a three-parameter rate-temperature formula has been fitted as follows: k=6.66×10-18T2.33 exp(-60.3/T) (in units of cm3 molecule-1 s-1).
ion kinetics of H atom with (CH3) 3GeH has been studied using ab initio molecular orbital theory. The kinetics calculation has been deduced using the canonical variational transition state theory (CVT) with the small-curvature tunneling correction method (SCT) over the temperature range of 200-3000 K. The CVT / SCT rate constants exhibit typical non-Arrhenius behavior, and a three-parameter rate-temperature formula has been fitted as follows: k = 6.66 × 10-18 T 2.33 exp (-60.3 / T ) in units of cm3 molecule-1 s-1).