The technics of combined treatment of ion nitrocarburizing-ion sulphurizing of CrMoCu alloy cast iron has been investigated and the compound layer with nitrocarbonide and sulphide has been made on the surface of CrMoCu alloy cast iron. The compound layer is composed of sulfide surface layer and the nitrocarbonide hypo-surface layer and its diffusing layer. The size of sulfide globular grains distributing equably on the surface is in nano-rnicron-scale, and the phase structure of the compound layer is composed of FeS^ FeSi^ Fe2C and Fe3N. Under dry sliding condition, the friction-reducing of sulphurized surface is good, but its function time can’t last very long. The nitrocarbonided+sulphurized surface can greatly improve the wear-resistance and the friction-reducing of CrMoCu alloy cast iron, and its integrated friction and wear properties are better than plain and sulphurized surfaces’. The technics of combined treatment of ion nitrocarburizing-ion sulphurizing of CrMoCu alloy cast iron has been investigated and the compound layer with nitrocarbonide and sulphide has been made on the surface of CrMoCu alloy cast iron. The compound layer is composed of sulfide surface layer and the nitrocarbonide hypo-surface layer and its diffusing layer. The size of sulfide globular grains distribute equably on the surface is in nano-rnicron-scale, and the phase structure of the compound layer is composed of FeS ^ FeSi ^ Fe2C and Fe3N. Under dry sliding condition, the friction-reducing of sulfurized surface is good, but its function time can not last very long. The nitrocarbonided + sulphurized surface can greatly improve the wear-resistance and the friction-reducing of CrMoCu alloy cast iron, and its integrated friction and wear properties are better than plain and sulphurized surfaces’.