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测定了过渡金属环戊二烯夹心化合物,(η~5-Cp)_2M(Cp=C_5H_5,M=Mn,Fe,Ru)的红外与激光拉曼光谱,在此基础上,用G-F矩阵法计算了这类化合物的力常数.讨论了Cp-M化学键的性质.
The infrared and laser Raman spectra of (η ~ 5-Cp) _2M (Cp = C_5H_5, M = Mn, Fe, Ru) were determined. Based on this, The force constants of these compounds are discussed. The properties of Cp-M chemical bonds are discussed.