重金属检测微纳传感器芯片批量制备与测试

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设计并制备了一种基于玻璃-硅微纳米结构的重金属检测微纳传感器芯片用于检测铅.传感器芯片集成了Ag/AgCl参比电极、三维金微阵列工作电极、金对电极以及微检测腔.该传感器采用微电子机械系统(MEMS)批量制备工艺,一批次同时制备多片4英寸(1英寸=2.54 cm)晶圆,而每片晶圆上有20个芯片.在优化的实验条件下,即最优沉积电压为-1V和最优沉积时间为240 s时,用方波溶出伏安法检测铅离子,信噪比为3时检测限达到0.82 μg·L-1.用同一批次制备的传感器,多次测量80 μg·L-1的铅离子,其重复性偏差为2.21%~3.35%,表明该新型微纳传感器具有良好的灵敏度和一致性,为水环境监测中大量布设重金属检测传感器节点提供了技术方案.
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