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采用水热法合成了一个新的分子式为[Pb(phen)2(NO3)]·NO3的金属-有机配合物(phen=1,10-邻啡啰啉),并对其进行了元素分析、红外光谱表征和X射线单晶衍射的结构解析.该配合物(C24H16N6O6Pb)属于单斜晶系,空间群为P21/n,晶体学数据:a=16.7035(12),b=7.7341(5),c=18.1198(13),β=98.1860(10),V=2317.0(3)3,Mr=691.62,Dc=1.983 g/cm3,μ(Mo Kα)=7.337 mm-1,F(000)=1328,Z=4.直接法解析原子位置的结果显示:R=0.0269,wR=0.0533.该配合物具有零维网状结构.
A new metal-organic complex of [Pb (phen) 2 (NO3)] · NO3 (phen = 1,10-o-phenanthroline) was synthesized by hydrothermal method and its elemental analysis was carried out. (C24H16N6O6Pb) belongs to the monoclinic system with the space group P21 / n. The crystallographic data are as follows: a = 16.7035 (12) , b = 7.7341 (5) (3) 3, Mr = 691.62, Dc = 1.983 g / cm3, μ (Mo Kα) = 7.337 mm-1, F = 18.1198 13, (000) = 1328, Z = 4. The results of the direct method for the resolution of the atomic position show: R = 0.0269, wR = 0.0533. The complex has a zero-dimensional network structure.