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The adsorption configurations of molecules adsorbed on substrates can significantly affect their physical and chemi-cal properties. A standing configuration can be difficult to determine by traditional techniques, such as scanning tunneling microscopy (STM) due to the superposition of electronic states. In this paper, we report the real-space observation of the standing adsorption configuration of phenylacetylene on Cu (111) by non-contact atomic force microscopy (nc-AFM). Deposition of phenylacetylene at 25 K shows featureless bright spots in STM images. Using nc-AFM, the line features representing the C–H and C–C bonds in benzene rings are evident, which implies a standing adsorption configuration. Fur-ther density functional theory (DFT) calculations reveal multiple optimized adsorption configurations with phenylacetylene breaking its acetylenic bond and forming C–Cu bond(s) with the underlying copper atoms, and hence stand on the substrate. By comparing the nc-AFM simulations with the experimental observation, we identify the standing adsorption configura-tion of phenylacetylene on Cu (111). Our work demonstrates an application of combining nc-AFM measurements and DFT calculations to the study of standing molecules on substrates, which enriches our knowledge of the adsorption behaviors of small molecules on solid surfaces at low temperatures.