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用ESR 方法探讨了在C60 与三乙胺(Et3 N) 的分子间电子转移反应中竹红菌乙素(HB) 的光催化作用.通过对Et3N/C60/HB 电子转移反应体系及其中间体的研究得知:在HB存在的条件下,可通过光催化电子转移反应机理,实现室温下由Et3N 到基态C60 的分子间电子转移
The ESR method was used to investigate the photocatalytic activity of hypocrellin B (HB) in the intermolecular electron transfer reaction between C60 and triethylamine (Et3N). Through the study on the electron transfer reaction system of Et3N / C60 / HB and its intermediates, we know that under the condition of HB, the intermolecular electron transfer from Et3N to the ground state C60 can be achieved by photocatalytic electron transfer reaction mechanism