我们在这里发表了两篇有关有机半导体导电机理的探讨性文章,两位作者的论点是不完全一致的。在第一篇里,作者综述了有机半导体导电机理的现有的三种论点,以及这些论点对现有的实验数据的合理解释,同时指出它们某些不足之处。作者根据现有资料对有机半导体的激活能和迁移率问题进行了讨论。作者认为,有机半导体的导电可理解为来源于π电子的载流子采取跳跃的方式而发生迁移的结果,由 We have published here two articles on the organic semiconductor conductive mechanism of the exploratory article, the two authors’ arguments are not entirely consistent. In the first article, the authors summarize the three existing arguments about the conductive mechanism of organic semiconductors and their reasonable explanations of available experimental data, noting some of their shortcomings. The authors discuss the activation energy and mobility of organic semiconductors based on available data. The authors believe that the conductivity of organic semiconductors can be understood as the result of the migration of π-derived carriers taking a jump,