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本文采用Ｆｅ＿３（ＣＯ）＿（１２）制备担载型络合物催化剂。采用程序升温反应技术考察了这类催化剂（ＣＯ＋Ｈ＿２）的反应性能，井使用紫外漫反射光谱和穆斯堡尔谱对催化剂进行了表征。经２５０℃和１５０℃还原的Ｆｅ／γ－Ａｌ＿２Ｏ＿３催化剂不仅活性远远高于４５０℃还原的Ｆｅ／γ－Ａｌ＿２Ｏ＿３，而且前者在反应过程中有乙烯和乙烷生成，后者则只有甲烷生成。经２５０℃还原的Ｆｅ／分子筛催化剂的活性高于４５０℃还原的Ｆｅ／分子筛催化剂，而且前者在反应过程中有乙烯、乙烷和丙烯生成，后者则只有甲烷生成。紫外漫反射谱和穆斯堡尔谱结果表明：较温和条件下活化的催化剂上有金属于属键骨架的存在。
In this paper, Fe_3 (CO) _ (12) was used to prepare supported complex catalysts. The reaction performance of these catalysts (CO + H 2) was investigated by temperature programmed reaction and the catalysts were characterized by UV diffuse reflectance spectroscopy and Mossbauer spectroscopy. The Fe / γ-Al 2 O 3 catalyst reduced at 250 ℃ and 150 ℃ is not only more active than Fe / γ-Al 2 O 3 reduced at 450 ℃, but also the former has ethylene and ethane during the reaction and the latter methane only. The activity of Fe / zeolite catalyst reduced at 250 ℃ was higher than that of Fe / zeolite catalyst reduced at 450 ℃, and the former produced ethylene, ethane and propylene during the reaction, while the latter only produced methane. UV diffuse reflectance spectroscopy and Mossbauer spectroscopy results show that: under milder conditions activated catalyst metal bond skeleton exists.