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The title compound, {[MnL2·(2,2-bipy)·H2O]·(HL)}, has been synthesized (HL = p-methoxybenzoic acid, 2,2-bipy = 2,2-bipyridine) by the reaction of MnCl2·6H2O with p-methoxybenzoic and 2,2-bipyridine in an alcohol-water solution. It crystallizes in the triclinic system, space group P1 with a = 10.1138(5), b = 11.2811(5), c = 16.2210(8) , α = 77.5920(10), β = 72.1890(10), γ = 66.2320(10)o, Mr = 683.56, V = 1603.65(13) 3, Z = 2, Dc = 1.416 g/cm3, F(000) = 710, μ = 0.473 mm-1, the final R = 0.0619 and wR = 0.1571 for 4724 observed reflections with I > 2σ(I). The structure determined demonstrated that it is an isomeric modification of the structure reported before. The Mn atom is six-coordinated by two N and four O atoms, forming a distorted octahedral geometry. All Mn–O and Mn–N distances range from 2.113(3)～2.410(3). There also exists a dissociative p-methoxybenzoic acid beside the octahedron.
The title compound, {[MnL2 · (2,2-bipy) · H2O] (HL)}, has been synthesized by the reaction of crystallinity in the triclinic system, space group P1 with a = 10.1138 (5), b = 11.2811 (5), c = 16.2210 ( , Α = 77.5920 (10), β = 72.1890 (10), γ = 66.2320 (10) o, Mr = 683.56, V = 1603.65 (13) 3, Z = 2, Dc = 1.416 g / cm3, F 000) = 710, μ = 0.473 mm-1, the final R = 0.0619 and wR = 0.1571 for 4724 observed reflections with I> 2σ (I). The structure determines the it is an isomeric modification of the structure reported before. Mn atoms are six-coordinated by two N and four O atoms, forming a distorted octahedral geometry. All Mn-O and Mn-N distances range from 2.113 (3) to 2.410 (3). There is also a dissociative p-methoxybenzoic acid beside the octahedron.