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The title complex [Mn(μ1,5-dca)2(POM)2] (C16H12MnN10O6,Mr = 495.30) has been prepared and structurally characterized. It crystallizes in triclinic,space group P1 with a = 7.4685(9),b = 7.5406(9),c = 9.8646(12) ,α = 83.202(2),β = 69.1200(10),γ = 79.4130(10)o,V = 509.38(11) 3,Z = 1,Dc = 1.602 g/cm3,F(000) = 249,μ(MoKa) = 0.704 mm-1,the final R = 0.0701 and wR = 0.2071 for 1615 observed reflections with I > 2σ(I). Each Mn(Ⅱ) exhibits a slightly distorted octahedral environment and connects with each other to form a one-dimensional complex by double bridging μ1,5-N≡C-N-C≡N ligands. The magnetic susceptibility of the title complex has been measured,and it displays weak antiferromagnetic interactions.
It crystallizes in triclinic space group P1 with a = 7.4685 (9), b = 1, Α = 83.202 (2), β = 69.1200 (10), γ = 79.4130 (10) o, V = 509.38 (11) 3, Z = 1 and Dc = 1.602 g / cm3, F (000) = 249, μ (MoKa) = 0.704 mm-1, the final R = 0.0701 and wR = 0.2071 for 1615 observed reflections with I> 2σ (I). Each Mn slightly distorted octahedral environment and connects with each other to form a one-dimensional complex by double bridging μ1,5-N≡CNC≡N ligands. The magnetic susceptibility of the title complex has been measured, and it displays weak antiferromagnetic interactions.