Extraction of Precious Metals with N,N'-Dimethyl-N,N'-Phenyl3-thiopentanediamide

来源 :The 6th International Conference on Hydrometallurgy(第六届国际湿法冶 | 被引量 : 0次 | 上传用户:ssm3695
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Precious metals are used widely in electronic industry because of their excellent heat resistance,corrosion resistance and catalytic property.Therefore it is important to recycle precious metals from E-waste.In this study, a new diamid extractant N,N-Dimethyl-N,N-didecyl-3-thiopentanediamide (MDTDGA) was firstly synthesized through N-alkylated and N-acylation reaction.The extraction behavior of precious metals with MDTDGA in 80% dodecane-20% 2-ethylhexanol from hydrochloric acid was studied.The extraction ration increases with HC1 concentration and extractant concentration,but it is not influenced by H+ concentration.It is indicated that the extraction of precious metals Pd(Ⅱ),Pt(Ⅳ), Au(Ⅲ) with MDTDGA is neutral coordination.High extraction efficiency of Au(Ⅲ) of 99.5% using MDTDGA was obtained.
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