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合成了含有水杨醛缩(4-甲氧基)苯氧乙酰腙(以下简写为 H2L)的锰配合物[Mn(L)(acac)-(EtOH)]?H2O (MnC23H29 N2O8, Mr = 516.42)。配合物晶体属三斜晶系, 空间群为 P1, 晶胞参数为:a = 7.6942(3), b = 11.2422(4), c = 14.9230(6) ?, α = 95.656(2), β = 104.848(2), γ = 95.642(2)°, V =1231.37(8) ?3, Z = 2, Dc = 1.393 g/cm3, μ = 0.585 mm–1, F(000) = 540。对于 4374 (I > 2σ(I)) 个可观察点, R = 0.0439, wR = 0.1150。在配合物中, 中心 Mn(III)离子具有扭曲的 NO5八面体配位构型。晶体通过分子内与分子间的氢键作用形成平行排列的无限双链结构。
(Mn (L) (acac) - (EtOH)] H2O (MnC23H29N2O8, Mr = 516.42) containing salicylidene (4-methoxyphenoxyacetylhydrazone) ). The complex crystal belongs to the triclinic system with the space group P1 and the unit cell parameters are a = 7.6942 (3), b = 11.2422 (4), c = 14.9230 (6) 104.848 (2), γ = 95.642 (2) °, V = 1231.37 (8)? 3, Z = 2, Dc = 1.393 g / cm3, μ = 0.585 mm-1 and F (000) = 540. For 4374 (I> 2σ (I)) observable points, R = 0.0439 and wR = 0.1150. In the complex, the central Mn (III) ion has a distorted NO5 octahedral coordination configuration. Crystal through the intramolecular and intermolecular hydrogen bonding to form a parallel arrangement of infinite double-stranded structure.