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A novel copper complex Cu2(L)4(1, HL = 2-ethoxy-6-([1,2,4]triazol-4-yliminomethyl)-phenol) has been synthesized and characterized by IR, single-crystal X-ray diffraction, and elemental analysis(CHN). The single crystal belongs to the triclinic system, space group P1 with a = 10.0991(10), b = 10.5280(12), c = 10.5777(11) ?, α = 97.230(9), β = 90.640(8), γ = 92.412(9)o, Mr = 1052.05, V = 1114.6(2) ?3, Z = 1, Dc = 1.567 g/cm3, F(000) = 542, μ = 1.029 mm–1, R = 0.0562 and w R = 0.1562. The fluorescence and electrochemiluminescence(ECL) of 1and HL ligand were studied. The luminescence properties of 1 can be attributed to the ligand-metal charge transfer.
A novel copper complex Cu2 (L) 4 (1, HL = 2-ethoxy- 6 - ([1,2,4] triazol- 4-yliminomethyl) -phenol) has been synthesized and characterized by IR, single- ray diffraction, and elemental analysis (CHN). The single crystal belongs to the triclinic system, space group P1 with a = 10.0991 (10), b = 10.5280 (12), c = 10.5777 ), β = 90.640 (8), γ = 92.412 (9) o, Mr = 1052.05, V = 1114.6 (2)? 3, Z = 1, Dc = 1.567 g / cm3, F (000) = 542, 1.029 mm-1, R = 0.0562 and w R = 0.1562. The fluorescence and electrochemiluminescence (ECL) of 1 and HL ligand were studied. The luminescence properties of 1 can be attributed to the ligand-metal charge transfer.