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采用三极管型等离子体增强化学汽相淀积(TriodePECVD)系统,适当选取硅烷(SiH4)和氢气(H2)流量比制备纳米硅(nc-Si:H)薄膜.保持栅极偏压为-100V,改变SiH4、H2流量比可以得到薄膜从非晶硅(a-Si:H)到nc-Si:H的结构转变,其氢气流量比例[H2]/([H2]+[SiH4])的阈值为93.3%.随着流量比进一步增大,晶化比例从12%增大至50%,但晶粒尺寸基本保持不变,nc-Si晶粒的平均尺寸约2.5nm,这是不同于常规二极管PECVD、氢稀释制备的nc-Si:H薄膜的新结果,并从实验上验证了电导率和电子迁移率的渗流现象.
A triode PECVD system was used to prepare the nc-Si: H thin film with the appropriate ratio of silane (SiH4) to hydrogen (H2). The gate bias was maintained at -100V. The SiH4 / H2 flow ratio was used to obtain the structure transition from amorphous silicon (a-Si: H) to nc-Si: H. ] + [SiH4]) is 93.3%. With the increase of flow ratio, the crystallization ratio increased from 12% to 50%, but the grain size remained unchanged, the average size of nc-Si grains was about 2.5nm, which is different from the conventional diode PECVD, Hydrogen dilution of the nc-Si: H film of the new results, and experimentally verified the conductivity and electron mobility of the seepage phenomenon.