目前的无机化学(或普通化学)在讲到活泼金属与浓硫酸的反应时,多举Zn、Fe、Al等的反应为例,谈及浓硫酸与金属钠(甚至ⅠA、ⅡA族金属)的反应所见甚少。个别的国外资料[Ⅰ]提到金属钠与浓硫酸反应的产物是硫酸钠,但未说明还原产物是什么,亦未说明反应机理。因而我们觉得这是无机化学教材内容和教学中的一个缺陷。为了丰富无机化学的 The current inorganic chemistry (or general chemistry) talks about the reaction of active metals with concentrated sulfuric acid, taking the reaction of Zn, Fe, Al, etc. as an example, and talking about concentrated sulfuric acid and metal sodium (even IA, IIA metals) Little reaction was seen. The individual foreign data [I] mentioned that the product of sodium metal reacted with concentrated sulfuric acid was sodium sulfate, but did not explain what the reduction product was and did not explain the reaction mechanism. Therefore, we think this is a flaw in the content and teaching of inorganic chemistry textbooks. In order to enrich inorganic chemistry