biPy相关论文
A New 3D Layered-pillared Cobalt(II)-organic Framework Constructed by Imidazole-4,5-dicarboxylic Aci
A new 3D metal-organic framework of {[Co3(IDC)2(bipy)2(py)2]·7H2O}n (1) was obtained by the hydrothermal reaction of Co......
在水热条件下利用间苯二乙酸,4,4’-二联吡啶和硝酸镉反应生成配位聚合物{[Cd(pda)(4,4’-bipy)(H2O)]·H2O}n(1)(1,3-H2pda=间苯......
通过水热合成技术合成了一个由经典的Keggin和pseudo-Keggin双阴离子,以4,4’-bipy为有机模板剂共同构筑成结构新颖的三维超分子化......
采用水热法合成了一个有机-无机杂化的Keggin型磷钼杂多化合物[H3PMo12O40]·2(4,4’-bipy)·1.75H2O(简称化合物1 bipy=联吡啶);......
Synthesis, Crystal Structure and Spectrum Properties of Trinuclear Manganese Coordination Compound M
A novel complex Mn3(2,2’-bipy)2(3,5-DMBA)6 with 3,5-dimethylbenzoic acid (3,5-DMBA) and 2,2’-bipyridine (2,2’-bipy) h......
为了探索π-π堆积作用和氢键对配合物的影响,本文以1,5-蒽醌二磺酸钠(简称Na2AQDS),2,2’—联吡啶(简称bipy)和Cd(II)离子进行混......
合成了一个新的铜配合物[{Cu(IBG)(2,2’-bipy)·H_2O}_2·5H_2O]_n,(H2IBG=1,3-二苯酰氨基酸;2,2’-bipy=2,2’-联吡啶),并且通过......
在水和乙醇的混合溶剂中合成了一维链状配合物[Zn(4,4′-bipy)(H2O)4]n·(Paba)2n(1)(4,4′-bipy=4,4′-联吡啶,PabaH=对氨基苯磺......
在400K的温度下,以Cd(NO_3)_2’4H_2O、CdBr_2、KBr、2,2’-联吡啶和Co(Ac)_2·4H_2O为原料,将其按化学计量比进行混合,在乙腈、氢......
采用溶剂热法,用H_3PMo_(12)O_(40)修饰三维金属有机框架材料Zn(BDC)(Bipy)_(0.5)构筑一例复合材料H_3PMo_(12)O_(40)/Zn(BDC)(Bip......
以H_6P_2Mo_(18)O_(62)、[Ni(2,2’-bipy)_3]Cl_2·5.5H_2O为原料,通过化学共沉淀法制备[Ni(2,2’-bipy)_3]_3(P_2Mo_(18)O_(62))......
碘化亚铜和4,4′-二联吡啶在溶液中反应的二种方法可制备出标题化合物的2个不同红色晶体,结构表征出两种晶体分别是单斜C2/c(1)和......
Synthesis, crystal structure and properties of binuclear manganese complex [(bipy)_2Mn_2(/J-O)(/i-Ac
Binuclear manganese complex [(bipy)2Mn2(μ-O)(μ-Ac)2(H2O)2](CIO4)2 was synthesized by the reaction of MnAc3 · 2H2O wi......
用紧束缚 (EHT)晶体轨道方法对层状金属配位聚合物 [{HgX2 (bipy) }n](X =Cl,Br ;bipy =4 ,4′ bipyridyl)进行了能带结构计算 ,并......
TG-DTG,IR和 SEM技术研究了 Eu2 ( BA) 6 ( bipy) 2 ,( BA=苯甲酸 ,bipy=2 ,2’-联吡啶 )配合物的热分解过程 ,运用 Achar法 ,Madh......
The title compound [Ni(bipy)3][(-oxo)Fe2Cl6] (bipy = 2, 2?bispyridine) was synthesized and its crystal structure was det......
合成了14种稀土元素与1,4—双(1′—苯基—3′—甲基—5′—氧代吡唑—4′—基)丁二酮—〔1,4〕(BPMPBD)和2,2′—联吡啶(BiPy)的......
稀土硝酸盐与双啮杂环胺配体α,α′联吡啶(bipy)的配合物研究不多.Hart 等合成了Ln(NO_3)_3(bipy)_2配合物;亦已解析了3个晶体结......
本文报道了La(NO_3)_3(bipy)(2H_2O)(B-15-C-5)(Mr=785.46)的合成和晶体结构。晶体属单斜晶系,空间群为P2_1/n。晶胞参数:a=11.951......
本文合成了稀土离子(Sm、Eu、Tb、Yb)与1-苯基-3-甲基-4-七氟丁酰基唑酮-5)及中性配体三苯基氧化膦、2,2—联吡啶、二甲基亚砜的三......
本文采用2,2-联二吡啶与氧心三核物[M_3O(C_2H_5COO)_6(H_2O)_3]·NO_3(M=Fe,Cr)在乙腈中反应的方法制备了两个簇合物:[Fe_4O_2(C2......
混合配体化合物分子内配体间的疏水缔合作用首次发现于1974年,由于生物配体分子常常含有不参与配位的疏水基团,它们在这些生物配......
本文研究了硝酸介质中痕量α,α′-bipy阻抑过二硫酸钾氧化甲基蓝褪色的新指示反应及其动力学条件,建立了动力学光度法测定α,α′-bipy的新方法......
Ligand Substituent Electronic Effect in Ternary Complexes—— Systems of Zn2+(Cd2+)-bipy(phen)-substit
Research has been done on the cooperating effect of π electronic transformation between the ligands in some transition......
利用不同溶剂合成并测定了希土三氯醋酸盐与α,α'-联吡啶(bipy)不同比例的配合物(Ⅰ)La:bipy=1:1,[La(CCl3COO)3(bipy)·H2O]2和(Ⅱ)Tb:bipy=1:2,Tb(CCl3COO)3(bipy)2·H2O,结构测定表明配合物(Ⅰ)与(Ⅱ)均为三斜晶系,中心离子......
迄今报道中,普遍认为Cu(bipy)_3Cl_2配合物是可以制得的,它具有配位数为6的八面体构型.在60年代,有人提出过异议,但因证据不充分,......
标题配合物式量M_r=979.91,单斜晶系C_(μ0)空间群,a=2.0413(4),b=2.5556(5),c=0.8926(3)nm,β=104.64(2)°,μ=14.44cm~(-1),T=29......
合成了富勒烯的电子模型物─丙烯酸甲酯联吡啶二碳基合钼的2个几何异构体,用X射线单晶衍射法测定了它们的晶体结构,研究了它们的红外......
标题配合物晶体属单斜晶系,P21/n空间群,晶胞参数a=1.4162(3)nm,b=1.5377(5)(nm),c=2.6017(5)nm,β=103.56(3°),Z=4。标题配合物是双核分子,4个苯甲酸的羧基桥联两个中心Eu(Ⅲ)离子。它们又分别与1个苯甲酸的......
1INTRODUCTIONControlingtheasemblyofmoleculesinthesolidisastimulatingscientificchalengeinthesynthesisoffunctionalmaterials,suc...
1INTRODUCTIONControllingtheasemblyofmoleculesinthesolidisastimulatingscientificchangengeheshesynthesisoffunctionalm......
Crystal Structure of Binuclear Manganese(Ⅲ) Complex with Schiff-base Ligand,〔Mn_2(C_(22)H_(22)N_2O_2
The title complex, [Mn2L2(EtOH)2 (bipy )](ClO4)2 (L=N,N’-ethylenebis (1-phenyl-3-imino-1-butanonato), bipy = 4, 4’-bip......
对结构相似的有机酸如:乳酸,丙氨酸,丙酮酸,草酸在Ru(bipy)2+3 /Ru(phen)2+3 -有机酸(HA)-CeⅣ(bipy= 2,2’-联吡啶, phen= 1,10-......
合成了新型镧系四元混合阴离子配合物〔La(C6H5COO)2(NO3)(bipy)〕2, 化学经验式为C24H18N3O7La,Mr= 599.33,晶体属三斜晶系,P1 空间群,晶胞参数:a=11.020(4), b= 11.182(2), c= 10.285(3) , α= 102.83(2), β= 109.16(2), γ=82.23(3)°, Z= 1 , Dc= 1.709 g/cm 3, V= 1164.7(6) 3, μ(MoKα)= 18.77cm ......
We have reported the synthesis of compounds mentioned in this paper and the characterization of their structure and pro......
根据Ru(bipy)_3~(2+)/Ru(phen)_3~(2+)-C_2O_4~(2-)-Ce~Ⅳ(bipy=2,2'-联吡啶,phen=1,10-邻菲咯琳)化学发光反应建立了该化学发光反......
在甲醇乙腈水介质中将邻菲咯啉( Phen)的 Cu(Ⅱ)、 Zn(Ⅱ)、 Pb(Ⅱ)配合物,2,2联吡啶( Bipy)的 Zn(Ⅱ)、 Pb(Ⅱ)配合物及乙二胺( En)的 Cu(Ⅱ)、 Zn(Ⅱ)配合物分别与 2,3二......
The title cluster compound [WS4Cu3Br(bipy)2] has been synthesized by the reaction of (NH4)2, CuBr and 2,2′ bipy in DMF......
The title compound {Cu2(pdc)2(4,4?-bipy)(H2O)3H2O}2 1 (H2pdc = pyridine-2,6- dicarboxylic acid, also known as dipicolini......
A novel coordination polymer, [Cu(m-BDOA)(bipy)·H2O]n (m-BDOA2-=benzene-1,3-dioxyacetate), was synthesized and characte......
The emission spectra of Ru(bipy)_2(dppx)~2+ in different environments has been studied. It was found that the solvent po......
A novel 1D coordination polymer of Mn(4-CPOA)(2,2-bipy)(H2O)n (4-CPOA2-=4-carboxylphenoxyac- etate) has been synthesized......