报道了一种新型混价铜配合物 [Cu Cu ( Ophen) 2 Cl]· H2 O( HOphen=2 -羟基 -1 ,1 0′-邻菲咯啉 )的水热合成和晶体结构 .该化合物属于三斜晶系 ,P1空间群 ,a=0 .91 667( 1 8) nm,b=1 .0 5 46( 2 ) nm,c=1 .1 70 5 ( 2 ) nm,α=80 .5 0 ( 3 )°,β=80 .5 6( 3 )°,γ=66.87( 3 )°,V=1 .0 2 0 2 ( 3 ) nm3,Z=2 ,Dc=1 .872 Mg/m3,R1 =0 .0 5 0 8,( w R2 ) =0 .1 481 .标题化合物由一种新型的双核铜配合物和一个结晶水组成 .邻菲咯啉在水热反应中发生羟基化 ,形成新型的羟基化邻菲咯啉 .两个这样的配合物通过 Cu…Cu间的范德华力相互作用形成二聚体 .二聚体之间通过 Ophen基团的 π-π堆积以及 C—H… Cl弱相互作用构筑成三维超分子网络 .水分子处于网络的孔穴中 .该化合物为邻菲咯啉的羟基化提供又一个新的范例 Reported the hydrothermal synthesis and crystal structure of a new Cu (Cu) (Ophen) 2 Cl] · H 2 O (HOphen = 2-hydroxy-1,1’-phenanthroline) Belongs to the triclinic system, space group P1, a = 0.91 667 (18) nm, b = 1.056 (2) nm, c = 1.705 (2) nm and α = 80. 5 0 (3) °, β = 80.56 (3) °, γ = 66.87 (3) °, V = 1.0202 (3) nm3, Z = 2, Dc = 1.872 Mg / m3, R1 = 0.0508, (w R2) = 0.1481 The title compound consists of a novel dinuclear copper complex and a crystal water, and phenanthroline undergoes hydroxylation in the hydrothermal reaction To form a novel hydroxylated phenanthroline. Two such complexes form dimers through van der Waals interactions between Cu ... Cu. The dimers are separated by π-π stacking of Ophen groups and C-H ... Weak interaction of Cl structures into a three-dimensional supramolecular network in which water molecules are located in the network. This compound provides yet another new paradigm for the hydroxylation of phenanthroline