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With transition metal complex, a discrete cuprous iodide compound, namely, [Ni(phen)_3]_2Cu_6I_(10)(1, phen = 1,10-phenanthroline) has been solvothermally synthesized and structurally characterized. Single-crystal X-ray diffraction studies revealed that compound 1 crystallizes in triclinic space group P1(No. 2) with a = 11.2694(2), b = 12.3699(3), c = 15.0387(3) ?, α = 102.840(2), β = 105.215(2), γ = 96.388(2)°, V = 1940.04(7) ?3, Z = 1, Dc = 2.438 g·cm~(-3), F(000) = 1324, R = 0.0256 and w R = 0.0555(I > 2σ(I)). Compound 1 features a discrete anionic moiety of [Cu6I10]~(4-) charge-balanced by two metal complexes of [Ni(phen)_3]~(2+). The optical absorption edge of compound 1 was estimated to be 2.24 eV. Interestingly, nearly 95% of contaminant(crystal violet aqueous solution(CV), 50 m L, 1.0 × 10~(-5) M) could be decolorized after exposure to visible light within 30 min, illustrating an impressive photocatalytic activity of compound 1. The thermal stability of 1 has also been studied.
Single-crystal X-ray diffraction (XRD) with transition metal complex, a discrete cuprous iodide compound, namely, [Ni (phen) 3] _2Cu_6I_ (10) (1,10- phenanthroline) has been solvothermally synthesized studies revealed that compound 1 crystallizes in triclinic space group P1 (No. 2) with a = 11.2694 (2), b = 12.3699 (3), c = 15.0387 (3), D = 2.438 g · cm -3, F (000) = 1324, R = 0.0256 and w R = 0.0555 (I> 2σ (I)). Compound 1 features a discrete anionic moiety of [Cu6I10] ~ (4-) charge-balanced by two metal complexes of [Ni edge of compound 1 was estimated to be 2.24 eV. Interestingly, nearly 95% of contaminant (crystal violet aqueous solution (CV), 50 m L, 1.0 × 10 -5 M) could be decolorized after exposure to visible light within 30 min, showing an impressive photocatalytic activity of compound 1. The thermal stability of 1 has also been been tudied.